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论文类型： 期刊论文

发表时间： 2014-02-01

发表刊物： CHINESE CHEMICAL LETTERS

收录刊物： SCIE、ISTIC、CSCD、Scopus

卷号： 25

期号： 2

页面范围： 364-366

ISSN号： 1001-8417

关键字： Ladder polymer; Solid contact; Ion-selective electrode; Copper

摘要： In recent years, there has been a pronounced interest in solid-contact ion-selective electrodes (SC-ISEs), with emphasis on the use of conducting polymers as ion-to-electron transducer. In this work, a ladder conjugated polymer, thieno[3,2-b]thiophene (LCPT), was investigated in fabricating Cu2+-selective electrodes for the first time. The resulting electrodes were characterized by electrochemical impedance spectroscopy (EIS), chronopotentiometry, and the water layer test. Results proved that the active LCPT facilitates the ion-to-electron transduction, and avoids the detrimental aqueous layer formed at the interface of SC-ISEs. (C) 2013 Shun-Yang Yu and Tao Xiong. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.