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DALIAN UNIVERSITY OF TECHNOLOGY Login 中文
LIU Xin

Associate Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates


Gender:Male
Alma Mater:Dalian University of Technology
Degree:Doctoral Degree
School/Department:School of Chemistry
Discipline:Physical Chemistry (including Chemical Physics). Inorganic Chemistry
Business Address:西部校区化工综合楼C307.
Contact Information:Email: xliu@dlut.edu.cn
E-Mail:xliu@dlut.edu.cn
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Current position: Xin Liu's Homepage >> Scientific Research >> Paper Publications

微孔[Me4N]2HgGe4S10的溶剂热合成与表征

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Indexed by:期刊论文

Date of Publication:2006-03-14

Journal:化学学报

Included Journals:SCIE、PKU、ISTIC、CSCD、Scopus

Volume:64

Issue:5

Page Number:371-374

ISSN No.:0567-7351

Key Words:溶剂热合成;晶体结构;开放骨架;热稳定性

Abstract:用溶剂热方法合成了[Me4N]2HgGe4S10,通过单晶X射线衍射,IR,DSC-TG手段对其进行了表征.结果表明,标题化合物属四方晶系,I-4空间群,晶胞参数a=0.92687(8)nm,c=1.43739(12)nmr,V=1.23484(18)nm3,Z=2,Mo Kαλ=0.071073 nm,R1=0.0570,wR2=0.1374,空旷骨架结构由超四面体Ge4S10与HgS4四面体共用顶点连接而成,有机模板离子在一维孔道中.该化合物具有一定的热稳定性,在320℃发生分解形成GeS2.

 

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