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Highly Sensitive and Selective Fluorescent Sensor for Distinguishing Cadmium from Zinc Ions in Aqueous Media

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Indexed by:期刊论文

Date of Publication:2009-04-02

Journal:ORGANIC LETTERS

Included Journals:SCIE、ESI高被引论文

Volume:11

Issue:7

Page Number:1655-1658

ISSN No.:1523-7060

Abstract:A fluorescent sensor, QA, based on acetamidoquinoline with DPA as receptor, was synthesized. In aqueous buffer solution, QA demonstrates high selectivity for sensing Cd(2+) with about 40-fold enhancement in fluorescence quantum yield and picomolar sensitivity (K(d) = 0.25 +/- 0.03 pM). Moreover, sensor OA can distinguish Cd(2+) from Zn(2+) via two different sensing mechanisms (PET for Cd(2+); ICT for Zn(2+)), and the discrimination is even possible by "naked eyes".

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