论文成果
From Stereochemically Tunable Homopolymers to Stereomultiblock Copolymers: Lewis Base Regulates Stereochemistry in the Coordination Polymerization of 2-Vinylpyridine
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- 论文类型：期刊论文
- 发表时间：2018-03-27
- 发表刊物：MACROMOLECULES
- 收录刊物：SCIE、EI
- 文献类型：J
- 卷号：51
- 期号：6
- 页面范围：2240-2246
- ISSN号：0024-9297
- 摘要：Excellent isoselectivity (mmmm > 99%) and high activity (TOF > 4000 h(-1) were achieved for the first time in the polymerization of the polar 2-vinylpyridine by using the simple lutetium-based catalysts, Lu(CH2SiMe3)(3)(THF)(x)(Py)(2-x) (x = 0, 1, 2). The isoselectivity (mm) of the polymer could be varied between 37% and 99% through simply altering the quantity of Lewis base (tetrahydrofuran, 1,4-diazabicyclo [2.2.2] octane, 3-bromopyridine, and pyridine) added. Moreover, a novel method for preparing isotactic-atactic stereomultiblock poly(2-vinylpyridine)s was developed by the addition and removal of THE during polymerization. The polymerization process including stereoselective control mechanism was deduced by DFT calculations.
