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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：吉林大学
学位：博士
所在单位：化学学院
学科：有机化学. 高分子化学与物理
办公地点：大连理工大学化学楼501
联系方式：Email:tqxu@dlut.edu.cn Phone:(0411)84708904
电子邮箱：tqxu@dlut.edu.cn
Controlled Divinyl Monomer Polymerization Mediated by Lewis Pairs: A Powerful Synthetic Strategy for Functional Polymers
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论文类型：期刊论文
发表时间：2014-09-01
发表刊物：ACS MACRO LETTERS
收录刊物：SCIE、Scopus
卷号：3
期号：9
页面范围：896-899
ISSN号：2161-1653
摘要：Lewis pair cooperation provides a facile approach for polymerizing dissymmetric divinyl polar monomers such as 4-vinylbenzyl methacrylate in excellent regioselectivity and high reactivity at mild conditions, affording soluble polymers bearing pendant active vinyl groups with high molecular weight (up to 6.4 x 10(5) g/mol) and narrow polydispersity (PDI < 1.5). ESI-TOF MS study demonstrated that the polymerization process only concerned the methacrylic double bond and selectively remained the pendant allylic or styrene C=C bond.