徐铁齐
个人信息Personal Information
教授
博士生导师
硕士生导师
性别:男
毕业院校:吉林大学
学位:博士
所在单位:化学学院
学科:有机化学. 高分子化学与物理
办公地点:大连理工大学化学楼501
联系方式:Email:tqxu@dlut.edu.cn Phone:(0411)84708904
电子邮箱:tqxu@dlut.edu.cn
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Probing Site Cooperativity of Frustrated Phosphine/Borane Lewis Pairs by a Polymerization Study
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论文类型:期刊论文
发表时间:2014-02-05
发表刊物:JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
收录刊物:SCIE、EI、Scopus
卷号:136
期号:5
页面范围:1774-1777
ISSN号:0002-7863
摘要:The first highly active phosphine (P)/borane (B) Lewis pair polymerization is promoted unexpectedly by P B adducts. The P and B site cooperativity is essential for achieving effective polymerization, as shown by this study examining the reactivity of a library of P/B Lewis pairs toward polymerization of a renewable acrylic monomer.