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论文类型：期刊论文

发表时间：2010-01-15

发表刊物：International Symposium on Catalysis

收录刊物：SCIE、EI、CPCI-S

卷号：149

期号：1-2

页面范围：196-201

ISSN号：0920-5861

关键字：2,6-Dimethylnaphthalene; HZSM-5; TEOS; Steam; Modification

摘要：Shape-selective methylation of 2-methylnaphthalene (2-MN) over HZSM-5 catalysts modified by steam and tetraethoxysilane (TEOS) treatments was carried out in a fixed-bed reactor Catalysis were characterized by XRD, NH(3)-TPD, BEL FT-IR spectra of pyndine adsorbed, and by adsorption of hexane and cyclohexane. The results show that the TEOS treatment can effectively passivate external active site and narrow pore mouth of catalyst. but it has less effect on I he internal surface than steam modification. Hydrothermal treatment can effectively reduce both external and internal acid sites, and adjust channel of catalyst Steam treatment can effectively increase the ratio of 2.6/2,7-DMN, but the ratio has no increasing trend on TEOS modified catalyst. So adjusting acidity property is more useful to increase the selectivity to 2,6-DMN and the ratio of 2,6/2,7-DMN than narrowing catalyst pore mouth. Tailoring acidic characteristics is more important than spatial control for distinguishing between 2,6-DMN and 2,7-DMN. (C) 2009 Elsevier B.V. All rights reserved.