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论文类型：期刊论文

发表时间：2016-07-01

发表刊物：JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS

收录刊物：SCIE、EI

卷号：64

页面范围：9-15

ISSN号：1876-1070

关键字：Coking benzene; Bio-ethanol; Ethylation; Nanosized HZSM-5

摘要：The ethylation of benzene, obtained from coke oven gas, with bio-ethanol over nanosized HZSM-5 zeolite catalyst was investigated in a down-flow fixed-bed reactor. X-ray diffraction, thermogravimetric analysis, ultraviolet raman spectrophotometry, ultraviolet visible spectrophotometry, and N-2 adsorption-desorption isotherms measurements were used to characterize catalyst morphology and coke deposit over the spent catalyst. Thiophene in coking benzene promoted the formation of coke. Water contained in bio-ethanol improved the catalyst selectivity and stability, inhibited coke formation and reduced its carbonization. The water also reduced both activity and desulfurization of the catalyst. The role of water in the reaction is due to its stronger adsorption on the active sites than ethanol and thiophene in the feed. (C) 2016 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.