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发表时间：2022-10-04

发表刊物：催化学报

卷号：40

期号：4

页面范围：477-485

ISSN号：0253-9837

摘要：The AEI cavity of SAPO-18 catalyst was modified with zinc cations with the conventional ion exchange procedure. The cavity modification effectively tunes the product selectivity, and shifts the products from mainly propylene to comparable production of ethylene and propylene in methanol to olefin (MTO) reaction. The incorporation of zinc ions and the generation of bicyclic aromatic species in the AEI cavity of SAPO-18 catalysts introduce additional diffusion hindrance that exert greater influence on the relatively bulky products (e.g. propylene and higher olefins), which increase the selectivity to small-sized products (e.g. ethylene). It appears that the incorporated zinc cations facilitate the generation of lower methylbenzenes which promote the generation of ethylene. The cavity modification via incorporating zinc ions effectively tunes the product selectivity over SAPO molecular sieves with relatively larger cavity, which provides a novel strategy to develop the potential alternative to SAPO-34 catalysts for industrial MTO reaction. (C) 2019, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

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