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论文类型：期刊论文

发表时间：2022-06-30

发表刊物：石油学报 石油加工

期号：4

页面范围：38-43

ISSN号：1001-8719

摘要：The process of i-propylalcohol oxidation to produce hydrogen peroxide, and propylene epoxidation catalyzed by TS-1 was studied. In i-propylalcohol oxidation, stable agent inhibits the decomposition of initiator to form free radicals. The i-propylalcohol oxidation activity strongly increased with the increase of temperature and the amount of initiator added; the oxygen partial pressure showed less effects on the oxidation activity, which increased with the increase of the oxygen partial pressure slightly. In the integrated reaction of i-propylalcohol oxidation and propylene epoxidation, hydrogen peroxide conversion and the yield of propylene oxide decreased with the reaction time as the amount of propylene oxide increased.

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