郭新闻

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教授

博士生导师

硕士生导师

主要任职:盘锦校区管委会副主任兼教学与科研工作部部长

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:工业催化. 物理化学

办公地点:化工实验楼B427

联系方式:18641143913

电子邮箱:guoxw@dlut.edu.cn

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Fabrication of hollow spheres by dry-gel conversion and its application in the selective hydrodesulfurization of FCC gasoline

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论文类型:期刊论文

发表时间:2013-04-15

发表刊物:JOURNAL OF COLLOID AND INTERFACE SCIENCE

收录刊物:SCIE、EI

卷号:396

页面范围:112-119

ISSN号:0021-9797

关键字:Hollow sphere; Dry-gel conversion; Selective hydrodesulfurization

摘要:Hollow spheres were synthesized from MCM-41 solid spheres by dry-gel conversion: It was found that water amount has a major impact on the formation of hollow spheres. Transmission electron microscopy (TEM) images revealed that the hollow spheres are between 500 and 600 nm in size with a dense shell of ca. 100 nm. The synthesized hollow sphere sample was examined as a support for hydrodesulfurization catalyst. The sulfur removal was enhanced while olefin hydrogenation of FCC gasoline was suppressed, and thus, the octane value was preserved when the hollow spheres (Na type) were loaded with Ni and Mo oxides as catalyst. (C) 2013 Elsevier Inc. All rights reserved.