郭新闻

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教授

博士生导师

硕士生导师

主要任职:盘锦校区管委会副主任兼教学与科研工作部部长

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:工业催化. 物理化学

办公地点:化工实验楼B427

联系方式:18641143913

电子邮箱:guoxw@dlut.edu.cn

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Synthesis and catalytic properties of hierarchical TS-1 in the presence of cationic organosilane surfactant

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论文类型:期刊论文

发表时间:2011-03-01

发表刊物:CHINESE CHEMICAL LETTERS

收录刊物:SCIE、ISTIC

卷号:22

期号:3

页面范围:303-305

ISSN号:1001-8417

关键字:Cationic organosilane surfactant; Hierarchical TS-1; Cyclohexene

摘要:Hierarchical TS-1 has been synthesized in the presence of cationic organosilane surfactant. The material is characterized with XRD, TEM, N(2) adsorption isotherm. The results show that the hierarchical TS-1 aggregates consist of small primary units with sizes of 20-30 nm. The BET surface area increases from 420 to 513 m(2)/g compared to conventional TS-1 zeolite. The sample is shown to be more active in epoxidation of cyclohexene than conventional TS-1. (C) 2010 Xin Wen Guo. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.