Indexed by:期刊论文
Date of Publication:2013-12-05
Journal:CATALYSIS COMMUNICATIONS
Included Journals:EI、SCIE、Scopus
Volume:42
Issue:42
Page Number:93-97
ISSN No.:1566-7367
Key Words:Formaldehyde; Catalytic oxidation; Au/gamma-Al2O3; Room temperature
Abstract:Au supported on gamma-Al2O3 prepared by deposition-precipitation (DP) using urea is found to be a highly active catalyst for the total oxidation of HCHO at room temperature under humid air, without the need for a reducible oxide as support. In-situ DRIFTS studies suggested that the surface hydroxyl groups played a key role in the partial oxidation of HCHO into the formate intermediates, which can be further oxidized into CO2 and H2O with participation of nano-Au. This study challenges the traditional idea of supporting noble metals on reducible oxides for HCHO oxidation at room temperature. (C) 2013 Elsevier B.V. All rights reserved.
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Associate Professor
Supervisor of Master's Candidates
Gender:Male
Alma Mater:Dalian Institute of Chemical Physics, CAS
Degree:Doctoral Degree
School/Department:Department of Chemical Engineering, Panjin
Discipline:Chemical Engineering. Physical Chemistry (including Chemical Physics)
Business Address:Center for Hydrogen Energy and Environmental Catalysis
Laboratory of Plasma Physical Chemistry
Dalian University of Technology
2 Linggong Road, Dalian 116024, China
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