论文类型：期刊论文
发表刊物：CHEMCATCHEM
收录刊物：Scopus、EI、SCIE
卷号：9
期号：16
页面范围：3191-3196
ISSN号：1867-3880
关键字：boranes; homogeneous catalysis; hydrogen; hydrolysis; iridium
摘要：For the homogeneous catalytic hydrolysis of ammonia borane (AB), a series of water-soluble proton-responsive iridium complexes bearing hydroxyl groups were utilized. Among the examined catalysts, [Cp*Ir(6,6'-(OH)(2)-bpy)(OH2)]SO4 exhibited the best catalytic performance in AB aqueous solution. Results obtained from experimental and theoretical studies revealed that hydrolysis of AB is assisted by synergistic effects between the pendent hydroxyl groups and the metal center.