论文名称：Anilido-oxazoline-ligated rare-earth metal complexes: synthesis, characterization and highly cis-1,4-selective polymerization of isoprene
论文类型：期刊论文
发表刊物：Dalton transactions (Cambridge, England : 2003)
收录刊物：PubMed
卷号：48
期号：11
页面范围：3583-3592
ISSN号：1477-9234
摘要：Anilido-oxazoline-ligated rare-earth metal dialkyl complexes have been synthesized and structurally characterized. The complexes exhibited strong fluorescence emissions and good catalytic performance on isoprene polymerization with high cis-1,4-selectivity. The treatment of anilido-oxazoline precursors ortho-C6H4[NH(2,6-R12C6H3)][C[double bond, length as m-dash]NC(R2,R3)CH2O] (R1 = R2 = R3 = Me (HL1); R1 = iPr, R2 = R3 = Me (HL2); R1 = R2 = iPr, R3 = H (HL3); and R1 = iPr, R2 = R3 = H (HL4)) with an equimolar amount of Ln(CH2SiMe3)3(THF)2 (Ln = Sc, Y) afforded rare-earth metal complexes L1-4-Ln(CH2SiMe3)2(THF)n (L1-Sc (1), n = 1; L2-Sc (2), n = 0; L1-Y (3), n = 1; L2-Y (4), n = 1; L3-Y (5), n = 1; and L4-Y (6), n = 1) in good yields. The complexes are stable in both the solid state and solution. Single crystal X-ray diffraction study showed that complexes 1, 3 and 4 exhibit a distorted trigonal bipyramidal configuration, while complex 2 is pseudo-tetrahedral without coordinated THF. The luminescence properties of complexes 1-4 were investigated and the emission maxima were found in the range of 465-477 nm. DFT and TD-DFT studies were carried out to explore their characteristic electronic structures and gain insight into their optical properties. Upon activation with organic borates, the reported complexes exhibited high activity and cis-1,4-selectivity for isoprene polymerization. The nature of the central metal and substituent groups in oxazoline have an influence on the cis-1,4-selectivity.
发表时间：2019-01-25