点击次数：

论文类型：期刊论文

发表时间：2017-10-04

发表刊物：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

收录刊物：SCIE、EI

卷号：56

期号：39

页面范围：11021-11027

ISSN号：0888-5885

摘要：Fe-doped carbon catalysts were prepared from Shenmu sub-bituminous coal with addition of Fe(NO3)(3) by KOH activation, and used for catalytic methane decomposition. The effects of Fe amount and carbonization/activation temperature on the structure and catalytic performance of resultant catalysts were investigated. The results showed that ferric nitrate mixed with coal could be directly reduced to Fe metal during the carbonization/activation process without a hydrogen reduction process. Methane conversion over Fe-doped carbon catalysts significantly increases as the amount of added Fe increases. When the amount of Fe added is 30 wt %, the resultant Fe-doped carbon has the highest catalytic activity and methane conversion increases from initial 20% to 58% at the reaction time of 9 h. Low carbonization temperature leads to high initial-conversion. The active sites of the Fe-doped carbon Catalysts prepared at higher temperature mainly come from metal Fe particles, thus leading to lower initial catalytic activity but better stability.