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论文类型：期刊论文

发表时间：2017-08-20

发表刊物：POLYMER CHEMISTRY

收录刊物：SCIE、EI、Scopus

卷号：8

期号：31

页面范围：4494-4502

ISSN号：1759-9954

摘要：This study demonstrates an efficient method for the synthesis of thermoreversible cross-linked ethylene/propylene rubbers (EPRs) via two steps; in the first step, a functional olefin monomer containing a furan group (FO) is designed and the ethylene/propylene/FO terpolymerization catalyzed by a traditional Ziegler-Natta catalyst is implemented; in the second step, a cross-linked network is constructed via Diels-Alder (DA) click reaction between the bismaleimide and pendant furan groups in the EPR chains. Via polymerization, the FO content in the copolymers was tailored in relatively wide range from 1.1 mol% to 9.7 mol%; this provided various cross-linking precursory groups for the DA reaction. Moreover, the cross-linking density could be adjusted via not only the amount of the inserted furan group but also the ratio of furan to bismaleimide. These solid thermoreversibile EP rubbers could perform their de-cross-linking above 110 degrees C and re-form the network below 85 degrees C in a heating-cooling cycle not only in the static measurement of FTIR, but also in the dynamic test of DMA. The mechanical properties of the resulting products with varied cross-linking densities were compared with that of the non-crosslinked polymer and proved to be of much higher modulus. This thermoreversible cross-linking behavior also provided a new strategy for local-repairing of any crack in rubber products.