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论文类型：期刊论文

发表时间：2017-07-01

发表刊物：JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS

收录刊物：SCIE、EI、Scopus

卷号：126

页面范围：194-200

ISSN号：0165-2370

关键字：Coal pyrolysis; Spark discharge plasma; Tar; CO2 reforming of methane

摘要：An integrated process of coal pyrolysis with CO2 reforming of methane by spark discharge plasma was developed to improve the tar yield of coal pyrolysis. The effects of the reactor configuration parameters and the integrated process conditions were investigated. It was found that the conversions of CH4 and CO2 and the selectivies of H-2 and CO increase with the discharge input power. The electrode with a large-diameter and long discharge gap are unbeneficial to conversion of CO2 and CH4. The reaction temperature has little effect on the conversion of reaction gases. In the integrated process, the tar and water yields increase with the pyrolysis temperature and holding time. The pyrolysis atmosphere remarkably influences the tar yield. Compared with the pyrolysis under N-2 (Py-N-2) or the mixture gas of CO2 and CH4 (Py-MG), the integrated process of CO2 reforming of CH4 with coal pyrolysis can produce more tar, which is ascribed to the interaction of activated CH4 by spark discharge plasma with the free radicals from coal pyrolysis. The tar yield is 1.4 times as Py-MG, and 1.5 times as Py-N-2 at the pyrolysis temperature of 550 degrees C.