点击次数：

论文类型：期刊论文

发表时间：2012-05-25

发表刊物：POLYMER

收录刊物：SCIE、EI

卷号：53

期号：12

页面范围：2315-2319

ISSN号：0032-3861

关键字：Early stages; Primary nucleation; Crystallization

摘要：Time-resolved synchrotron small angle X-ray scattering (SAXS) was used to investigate the early stages of crystallization in melt crystallized polyethylene. Classic Gibbs nucleation or density fluctuation theory can be used to describe the primary nucleation mechanism. At 110 degrees C, no signal of crystallization can be detected by SAXS for 30 min. When it is lower than 110 degrees C, the low q scattering intensity (0.008 <q <0.03 angstrom(-1)) begins to upturn, and the primary nucleation process starts. The measured fractal dimension of the critical nuclei is in the vicinity of 3 which is close to the prediction of classic Gibbs nucleation theory. The growth rate of density fluctuations R(q) at different scattering vector q for different temperatures was obtained by analyzing the increase of scattering intensities. The results show that the growth rate of density fluctuation gets much bigger with the decrease of the isothermal crystallization temperature, but there is no signal of spinodal decomposition mechanism, in which there should be a linear relationship between R(q)/q(2) and q(2). (C) 2012 Elsevier Ltd. All rights reserved.