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个人信息Personal Information
副教授
博士生导师
硕士生导师
任职 : 化环生学部研究生助理
性别：女
毕业院校：华中科技大学
学位：博士
所在单位：化工学院
学科：化学工艺. 能源化工. 热能工程
办公地点：大连理工大学西部校区化工实验楼C431
联系方式：0411-84986160
电子邮箱：yli@dlut.edu.cn
Ruthenium(II) complex catalysts bearing a pyridyl-supported pyrazolyl-imine ligand for transfer hydrogenation of ketones
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论文类型：期刊论文
发表时间：2009-09-01
发表刊物：JOURNAL OF ORGANOMETALLIC CHEMISTRY
收录刊物：SCIE、EI、Scopus
卷号：694
期号：19
页面范围：3068-3075
ISSN号：0022-328X
关键字：Arylimino; Pyrazolylpyridine; Ruthenium; Transfer hydrogenation; Ketones
摘要：A new class of hemilabile unsymmetrical 2-(1-arylimino)-6-(pyzazol-1-yl)pyridine ligands and their ruthenium(II) and nickel(II) NNN complexes were synthesized. The Ru(II) complex catalysts have been fully characterized and exhibited good to excellent catalytic activity in the transfer hydrogenation (TH) of ketones in refluxing 2-propanol. These results have demonstrated rare examples of active ruthenium(II) NNN complex catalysts that do not feature a N-H functionality for TH of ketones. (C) 2009 Elsevier B. V. All rights reserved.