个人信息Personal Information
副教授
硕士生导师
性别:女
毕业院校:北京师范大学
学位:硕士
所在单位:化学学院
学科:无机化学
办公地点:大连理工大学化工综合楼C410
联系方式:inchem@dlut.edu.cn
电子邮箱:inchem@dlut.edu.cn
A heptanuclear heterotrimetallic [Na2Cr2Tb3] cluster exhibiting single-molecule magnet behavior
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论文类型:期刊论文
发表时间:2013-11-01
发表刊物:INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物:SCIE、Scopus
卷号:37
页面范围:202-205
ISSN号:1387-7003
关键字:Heptanuclear; Heterotrimetallic; Maleic acid; Bicapped trigonal bipyramid; Slow relaxation of the magnetization
摘要:With maleic acid as the ligand, a heterotrimetallic cluster {[Na(H2O)][Na2Cr2Tb3(mu(3)-OH)(6)(L)(6)(H2O)(17)]}center dot 16H(2)O (H2L = maleic acid) (1) bearing a bicapped trigonal bipyramidal [Na2Cr2Tb3] metal skeleton was synthesized and characterized. Magnetic measurements indicate that 1 displays overall ferromagnetic interactions and slow relaxation of the magnetization. (C) 2013 Elsevier B.V. All rights reserved.