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论文类型：期刊论文

发表时间：2017-12-01

发表刊物：ACS OMEGA

收录刊物：SCIE

卷号：2

期号：12

页面范围：9199-9210

ISSN号：2470-1343

摘要：Nitrogen-containing organic chemicals such as amines, amides, nitriles, and hydrazones are crucial in chemical and medical industries. This paper reports a direct synthesis of N,N-dimethyl cyanamide [(CH3)(2)NCN]and amino acetonitrile (NH2CH2CN) through a methane/ammonia (CH4/NH3) coupling reaction triggered by dielectric barrier discharge plasma, with by-products of hydrazine, amines, and hydrazones. The influence of CH4/NH3 molar ratio, feedstock residence time, and specific energy input on the CH4/NH3 plasma coupling reaction has been investigated and discussed. Under the optimized conditions, the productivities of (CH3)(2)NCN and NH2CH2CN reached 0.46 and 0.82 g.L-1.h(-1), respectively, with 8.83% CH4 conversion. In addition, through combining the optical emission spectra diagnosis and the reaction results, a possible CH4/NH3 plasma coupling reaction mechanism has been proposed. This paper provides a potential fine application of CH4 and NH3 in green synthesis of liquid nitrogen-containing organic chemicals, such as nitriles, amines, amides, and hydrazones.