张守海

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:高分子材料. 高分子化学与物理. 膜科学与技术

联系方式:0411-84986107

电子邮箱:zhangshh@dlut.edu.cn

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Preparation and properties of novel sulfonated copoly (phthalazinone biphenyl ether sulfone) composite nanofiltration membrane

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论文类型:期刊论文

发表时间:2013-06-03

发表刊物:DESALINATION

收录刊物:SCIE、EI

卷号:318

页面范围:56-63

ISSN号:0011-9164

关键字:Sulfonated copoly (phthalazinone biphenyl ether sulfone); Composite membranes; Nanofiltration; Membrane property

摘要:Thin composite nanofiltration membranes with improved thermal stability were prepared by coating sulfonated copoly (phthalazinone biphenyl ether sulfone) (SPPBES) on poly (phthalazinone ether sulfone ketone) ultrafiltration support membranes. The effects of polymer concentration, degree of sulfonation of SPPBES, crosslinking agent, curing treatment temperature and curing time on the performance of composite membranes were investigated. The membrane prepared under the optimum condition exhibited a permeate flux of 73 L/m(2)h and 84% rejection of Na2SO4 at 1.0 MPa and 20 degrees C. Moreover, these membranes showed good stability against chemical attack and high tolerance to chlorine. When the temperature of feed solution increased from 20 to 90 degrees C, solution permeate flux increased three-fold while the rejection of the membrane decreased by 2%. (C) 2013 Elsevier B.V. All rights reserved.