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论文类型：期刊论文

发表时间：2013-10-21

发表刊物：JOURNAL OF MATERIALS CHEMISTRY A

收录刊物：SCIE、EI、Scopus

卷号：1

期号：39

页面范围：12246-12254

ISSN号：2050-7488

摘要：Poly(phthalazinone ether ketone ketone) anion exchange membranes with pyridinium as anion exchange groups (PyPPEKK) were prepared by reacting chloromethylated poly(phthalazinone ether ketone ketone) membranes with pyridine in solution. The reaction conditions including diluent solvents, pyridine concentration, reaction time and temperature were investigated. Under the optimized reaction condition, PyPPEKK anion exchange membranes with IEC values in the range of 0.96-1.55 mmol g(-1) and water uptake in the range of 10.2-16.5% were obtained. The swelling ratio of PyPPEKK membranes in deionized water and VOSO4 solution were in the range of 3.2-10.6% and 2.5-7.8%, respectively. PyPPEKK membranes showed good chemical stability in VO2+ solution. Notably, PyPPEKK membranes had higher coulombic efficiencies of VRB and much lower vanadium permeability compared with Nafion117 membrane. The energy efficiency of VRB with PyPPEKK membrane reached 83.6% at 80 mA cm(-2) while the energy efficiency of VRB with Nafion117 membrane was 80.7% at the same charge-discharge current density. Furthermore, PyPPEKK membrane exhibited good performance in the 100-cycle charge-discharge VRB test.