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论文类型：期刊论文

发表时间：2012-11-01

发表刊物：JOURNAL OF POWER SOURCES

收录刊物：SCIE、EI、Scopus

卷号：217

页面范围：296-302

ISSN号：0378-7753

关键字：Vanadium redox flow battery; Anion exchange membrane; Chloromethylation; Poly(phthalazinone ether ketone ketone)

摘要：To develop cost-effective membranes with low permeability of vanadium ions for vanadium redox flow battery (VRB) application, an inexpensive precursor membrane material, chloromethylated poly(phthalazinone ether ketone ketone), is first prepared from poly(phthalazinone ether ketone ketone) with nitrobenzene as the solvent, and then reacted with trimethylamine to form quaternized poly(phthalazinone ether ketone ketone) (QAPPEKK) anion exchange membranes. At an ion exchange capacity of 1.56 mmol g(-1), the QAPPEKK membrane shows much lower permeability of vanadium ions (0.17 x 10(-4) cm min(-1) for V3+ and 0.21 x 10(-4) cm min(-1) for VO2+) than that of Nafion117 membrane (1.34 x 10(-4) cm min(-1) for V3+ and 1.19 x 10(-4) cm min(-1) for VO2+), resulting in higher coulombic efficiency (99.4% at 80 mA cm(-2)). In addition, the energy efficiency of the VRB with QAPPEKK membrane is comparable to that of VRB with Nafion117 membrane. Moreover, the QAPPEKK membrane is stable in VO2+ electrolyte, and exhibits good performance in the 100-cycle charge-discharge test of VRB. (C) 2012 Elsevier B.V. All rights reserved.