张守海

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:高分子材料. 高分子化学与物理. 膜科学与技术

联系方式:0411-84986107

电子邮箱:zhangshh@dlut.edu.cn

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Effect of additives on the performance and morphology of copoly (phthalazinone ether sulfone) UF membrane

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论文类型:期刊论文

发表时间:2012-03-30

发表刊物:DESALINATION

收录刊物:SCIE、EI

卷号:290

页面范围:67-73

ISSN号:0011-9164

关键字:Copoly (phthalazinone ether sulfone) (PPBES); Ultrafiltration membrane; Preparation; Morphology; Additive

摘要:Copoly (phthalazinone ether sulfone) (PPBES) is a novel material with excellent thermal resistance and good flexibility. PPBES ultrafiltration (UF) membranes were prepared with phase inversion method when N, N-dimethylacetamide (DMAc) was used as solvent and water was used as coagulation bath. Effects of different additives such as ethylene glycol monomethyl ether (EGME), glycol, propanol, butanone and ether on the performance and morphology of PPBES UF membrane were studied in detail. With the increase of additive concentration, the performance and morphology of the UF membrane changed due to the physical property of the additive and the mutual effect between the additive and non-solvent water. It was concluded that the polarity and volatility of the additive play important roles in the membrane performance and morphology. Additive with strong polarity is ready to form membrane with spongy structure. Additive with high volatility endows with membrane high rejection and low flux. (C) 2012 Published by Elsevier B.V.