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个人信息Personal Information
教授
性别:男
出生日期:1987-10-06
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
学科:精细化工. 应用化学
办公地点:精细化工全国重点实验室知顺楼E504
电子邮箱:xuanzhang@dlut.edu.cn
个人简介Personal Profile
张譞,大连理工大学精细化工全国重点实验室教授,博士生导师。2008年获中国石油大学(北京)学士学位; 2014年1月获大连理工大学博士学位(导师:包明教授、何仁教授);先后在日本东北大学分子原子高等研究机构(2014-2015年,导师:Yoshinori Yamamoto教授)和美国科罗拉多州立大学化学系(2015-2019年,导师:Andrew McNally教授)做博士后研究;2020-至今先后在南京信息工程大学、大连理工大学工作。获国家海外高层次引才计划青年项目(2021年)、获江苏特聘教授(2020年)、江苏双创人才(2021年),现担任中国化学会均相催化专委会委员、中国化工学会硅能源与化工专委会委员、Chinese Chemical Letters期刊青年编委,主持参与国家自然科学基金面上项目、国家自然科学基金青年项目、江苏省社会发展重点项目、贵州省教育厅创新团队等多项国家及省部级项目。研究兴趣涉及绿色能源驱动(光、电催化)惰性化学键的活化与转化,有机硅、锗化学,CO2活化及转化。秉承“大宗化学品的高值化转化”研究理念,围绕不饱和烃参与的新反应,构建具有应用前景的有机分子。在Nature, Science, Nat. Commun., Angew. Chem. Int. Ed., ACS Catal.等国际重要期刊发表SCI论文30余篇,部分工作被C&EN、Chemistry World、Phys. Org等国际媒体进行了报道,并被Chem、Synfacts、Org. Process Res. Dev.等杂志作为亮点进行了评述。
代表性论文:
1. Xuan Zhang#, Kyle G Nottingham#, Chirag Patel, Juan V Alegre-Requena, Jeffrey N Levy, Robert S Paton*, Andrew McNally*, Phosphorus-Mediated sp2-sp3 Couplings for C-H Fluoroalkylation of Azines. Nature 2021, 594, 217-222. (Previewed by Chem, 2021, 7, 1420).
2. Michael C. Hilton, Xuan Zhang#, Benjamin T. Boyle#, Juan V. Alegre-Requena, Robert S. Paton*, Andrew McNally*, Heterobiaryl synthesis by contractive C–C coupling via P(V) intermediates. Science 2018, 362, 799–804. (Featured in: C&EN, Chemistry World, Phys.org, and Synfacts 2019, 15, 0117).
3. Rui Gu, Xiujuan Feng, Ming Bao*, and Xuan Zhang*. Modular access to alkylgermanes via reductive germylative alkylation of activated olefins under nickel catalysis. Nat. Commun. 2023, 14, 7669.
4. Jinwei Sun,# Yongze Zhou,# Rui Gu,# Xin Li, Ao Liu and Xuan Zhang*. Regioselective Ni-Catalyzed Reductive Alkylsilylation of Acrylonitrile with Unactivated Alkyl Bromides and Chlorosilanes. Nat. Commun. 2022, 13, 7093.
5. Zeyou Wang#, Ziye Wei#, Shouhui Liu, Chenxuan Xu, Xijuan Yao, Lifei Han, Xiujuan Feng, Ming Bao, Weili Si*, Xuan Zhang*. Modular Assembly of Aldehydes, Styrenes and CO2 for the Synthesis of γ-Hydroxy Acids under Organophotocatalysis. Sci. China Chem. 2025, DOI: 10.1007/s11426-025-2687-5.
6. Siqi Jian, Jing Wang, Xiujuan Feng*, Ming Bao, Xuan Zhang*. Visible-Light-Driven Synthesis of Sulfinamides via Deoxygenative Sulfinamidation of Alcohols with N‑Sulfinyltritylamine. Org. Lett. 2025, 27, 7212−7217.
7. Hui Yin,‡ Siqi Jian,‡ Xiujuan Feng,* Ming Bao and Xuan Zhang*. Metal-free photoinduced denitrogenative alkylation of vinyl azides with alkyl radicals toward ketones. Org. Chem. Front. 2024, 11, 3124-3130.
8. Bei Zhang, Xuan Zhang*, Jian Wang*. Recent Progress in Carbene-Catalyzed Fluoroalkylation. Sci. China Chem. 2024, 67, 2448–2460.
9. Xin Li,§ Yan Jiao,§, Lifei Han*, Jinwei Sun, Xuan Zhang*. Defluorinative alkylation of 1-trifluoromethyl alkenes with alkyl radicals derived from visible light-induced deoxygenation of xanthate salts: synthesis of gem-difluoroalkenes. Org. Biomol. Chem. 2023, 21, 3330–3334.
10. Zhuqian Cai,† Rui Gu,† Weili Si,* Yubin Xiang, Jinwei Sun, Yan Jiao, Xuan Zhang*. Photoinduced Allylic Defluorinative Alkylation of Trifluoromethyl Alkenes with Katritzky Salts under Catalyst- and Metal-Free Conditions. Green Chem. 2022, 24, 6830-6835.
11. Xin Li,§ Weili Si,§ Zhanhui Liu, Haitao Qian, Tingxue Wang, Shengnan Leng, Jinwei Sun, Yan Jiao, Xuan Zhang*. Visible-Light-Promoted Desulfurative Alkylation of Alkyl Thianthrenium Salts with Activated Olefins. Org. Lett. 2022, 24, 4070–4074.
12. Xuan Zhang, Andrew McNally*, Cobalt-Catalyzed Alkylation of Drug-Like Molecules and Pharmaceuticals Using Heterocyclic Phosphonium Salts. ACS Catal. 2019, 9, 4862-4866.
13. Xuan Zhang, Andrew McNally*, Phosphonium Salts as Pseudohalides: Regioselective Nickel-Catalyzed Cross-Coupling of Complex Pyridines and Diazines. Angew. Chem. Int. Ed. 2017, 56, 9833–9836. (Very Important Paper; Most Accessed 07/2017; Highlighted by Org. Process Res. Dev. 2017, 21, 1196–1208).
14. Xuan Zhang, Zhanqiang Xu, Weili Si, Kazuaki Oniwa, Ming Bao, Yoshinori Yamamoto, Tienan Jin*, Synthesis of extended polycyclic aromatic hydrocarbons by oxidative tandem spirocyclization and 1,2-aryl migration, Nat. Commun. 2017, 8, 15073. (Highlighted by Synfacts 2017, 13, 0698).