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论文类型：期刊论文

发表时间：2019-06-01

发表刊物：THERMOCHIMICA ACTA

收录刊物：SCIE、EI

卷号：676

页面范围：20-26

ISSN号：0040-6031

关键字：Density; Magnetic suspension balance; Carbon dioxide; Impurities; GERG-2008 EOS

摘要：As a thermodynamic property, the density of CO2 mixtures plays an important role on carbon capture and storage. The densities of two CO2/N-2/O-2 ternary mixtures were measured at temperatures from (300.15-353.15) K and pressures from (5-18) MPa using a high-precision magnetic suspension balance. The temperature and pressure uncertainties were 0.01 K and 0.005 MPa, respectively. The density measurement uncertainty was estimated as 0.138 kg.m(-3). Impurities decreased the density of pure CO2 and the more the impurities were, the larger the reduction was. The densities of mixtures were calculated using GERG-2008 EOS and compared with experimental data. When the temperature and pressure were far away from the critical region, the discrepancy between the experimental data and GERG-2008 EOS calculations was small.