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论文类型：期刊论文

发表时间：2009-07-15

发表刊物：JOURNAL OF HAZARDOUS MATERIALS

收录刊物：SCIE、EI、PubMed

卷号：166

期号：1

页面范围：547-552

ISSN号：0304-3894

关键字：TiO2 nanotube; Salicylic acid; Photoelectrocatalysis; Nitrophenol; Modification

摘要：This research focused on immersion method synthesis of visible light active salicylic acid (SA)-modified TiO2 nanotube array electrode and its photoelectrocatalytic (PEC) activity. The SA-modified TiO2 nanotube array electrode was synthesized by immersing in SA solution with an anodized TiO2 nanotube array electrode. Scanning electron microscope (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), infrared spectroscopy (IR), UV-vis diffuse reflectance spectrum (DRS), and Surface photovoltage (SPV) were used to characterize this electrode. It was found that SA-modified TiO2 nanotube array electrode absorbed well into visible region and exhibited enhanced visible light PEC activity on the degradation of p-nitrophenol (PNP). The degradation efficiencies increased from 63 to 100% under UV light, and 79-100% under visible light (lambda > 400 nm), compared with TiO2 nanotube array electrode. The enhanced PEC activity of SA-modified TiO2 nanotube array electrode was attributed to the amount of surface hydroxyl groups introduced by SA-modification and the extension of absorption wavelength range. (C) 2008 Elsevier B.V. All rights reserved.