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论文类型：期刊论文

发表时间：2008-06-04

发表刊物：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

收录刊物：SCIE、EI

卷号：47

期号：11

页面范围：3804-3808

ISSN号：0888-5885

摘要：Highly ordered boron-doped TiO2 nanotube arrays were fabricated via a facile electrodeposition method. X-ray photoelectron spectroscopy (XPS) analysis revealed incorporated B atoms in the lattice of a TiO2 nanotube array. The X-ray diffraction (XRD) spectrum indicated improved crystallinity of boron-doped TiO2 nanotube arrays, relative to undoped TiO2 nanotube arrays. A shift of the absorption edge toward the Visible region and a new absorption shoulder (380-510 nm) of boron-doped TiO2 nanotube arrays were observed via diffuse reflectance spectroscopy (DRS). In photoelectrochemical measurements, under either ultraviolet (UV) or visible-light irradiation, the photocurrent conversion efficiency was enhanced because of boron doping. The photoelectrocatalysis of phenol under simulated solar irradiation was performed using boron-doped or undoped TiO2 nanotube arrays, and the kinetic constant of a boron-doped TiO2 nanotube array photoelectrode was increased by ca. 28% compared to that of an undoped TiO2 nanotube array photoelectrode.