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发布时间：2019-03-09

论文类型：期刊论文

发表时间：2010-12-01

发表刊物：CRYSTAL GROWTH & DESIGN

收录刊物：Scopus、EI、SCIE

卷号：10

期号：12

页面范围：5020-5023

ISSN号：1528-7483

摘要：Two new mixed ligand metal organic frameworks, [Cu-2(OH)(2,2' bipy)(2)(BTC) 2H(2)O](n) (1) and [Co(4 4' bipy) (m BDC)](n) (2) have been synthesized by hydrothermal reaction of Cu(COO)(2) H2O with 1 3 5 benzenetricarboxylic acid (H3BTC) and 2 2' bipyridine and of Co(NO3)(2) 6H(2)O with 1 3 benzenedicarboxylic acid (m H2BDC) and 4,4' bipyridine respectively They were characterized by single crystal X ray diffraction analysis powder XRD, elemental analysis TGA, and IR spectroscopy The adsorption characteristics of compounds 1 and 2 for methanol were investigated in situ with a quartz crystal microbalance (QCM) which indicated that they were highly sensitive to methanol at room temperature