Associate Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates
Paper Publications
Palladium-Catalyzed Regioselective and Diastereoselective C-Glycosylation by Allyl-Allyl Coupling
Hits:
Indexed by:Journal Article
Date of Publication:2021-03-13
Journal:ADVANCED SYNTHESIS & CATALYSIS
Volume:363
Issue:3
Page Number:846-850
ISSN:1615-4150
Key Words:C-glycosylation; Allyl-allyl coupling; Pd-π -allyl intermediate; Achmatowicz rearrangement products; Methylcoumarins
Abstract:A Pd-catalyzed C-glycosylation reaction was developed by allyl-allyl coupling process using Achmatowicz rearrangement products as donors and methylcoumarins as acceptors under mild conditions. This method featured regio- and diastereoselectivities, stereodivergent synthesis of C-glycosides. The glycosyl donors with controlled stereodiversity and glycosyl acceptors with fluorescent performace further highlighted this methodology.