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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：大连工学院
学位：学士
所在单位：化工学院
学科：工业催化. 化学工艺
办公地点：大连理工大学西校区化工实验楼B221
联系方式：凌工路2号大连理工大学西校区化工实验楼B221,116023 tel：041184986322，email：zalidy5518@vip.sina.com
电子邮箱：zhangyc@dlut.edu.cn
Catalytic Hydrogenation of CO2 to Methanol: Study of Synergistic Effect on Adsorption Properties of CO2 and H-2 in CuO/ZnO/ZrO2 System
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论文类型：期刊论文
发表时间：2015-12-01
发表刊物：CATALYSTS
收录刊物：SCIE、Scopus
卷号：5
期号：4
页面范围：1846-1861
ISSN号：2073-4344
关键字：methanol synthesis; CO2 conversion; synergetic effect; medium basic site; citrate method
摘要：A series of CuO/ZnO/ZrO2 (CZZ) catalysts with different CuO/ZnO weight ratios have been synthesized by citrate method and tested in the catalytic hydrogenation of CO2 to methanol. Experimental results showed that the catalyst with the lowest CuO/ZnO weight ratio of 2/7 exhibited the best catalytic performance with a CO2 conversion of 32.9%, 45.8% methanol selectivity, and a process delivery of 193.9 g(MeOH)center dot kg(cat)(-1).h(-1). A synergetic effect is found by systematic temperature-programmed-desorption (TPD) studies. Comparing with single and di-component systems, the interaction via different components in a CZZ system provides additional active sites to adsorb more H-2 and CO2 in the low temperature range, resulting in higher weight time yield (WTY) of methanol.