张永春

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:大连工学院

学位:学士

所在单位:化工学院

学科:工业催化. 化学工艺

办公地点:大连理工大学西校区化工实验楼B221

联系方式:凌工路2号大连理工大学西校区化工实验楼B221,116023 tel:041184986322,email:zalidy5518@vip.sina.com

电子邮箱:zhangyc@dlut.edu.cn

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Synthesis of micron-sized hollow silica spheres with a novel mesoporous shell of MCF

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论文类型:期刊论文

发表时间:2009-07-01

发表刊物:CHINESE CHEMICAL LETTERS

收录刊物:SCIE、ISTIC、CSCD

卷号:20

期号:7

页面范围:852-856

ISSN号:1001-8417

关键字:Hollow spheres; MCF; Mesoporous material

摘要:Micron-sized hollow silica spheres whose shells are made up of mesocellular silica foams (MCFs) have been synthesized by one-pot sol-gel method in benzene/water/P123 emulsion. The material is characterized with SEM, TEM, BET and (29)Si MAS NMR. The results show that the MCFs of the unique shell of hollow silica spheres were connected by large windows with a narrow distribution of similar to 10 nm in diameter, the inner space of the hollow sphere is accessible. And the formation mechanism of the hollow silica spheres is proposed. (C) 2009 Xin Wen Guo. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.