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论文类型：期刊论文

发表时间：2014-06-01

发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS

收录刊物：SCIE、Scopus

卷号：44

页面范围：169-172

ISSN号：1387-7003

关键字：Hydrothermal synthesis; Indium sulfide; Template effect; Crystal structure

摘要：Two indium sulfides [(Me)(4)N](6)[In10S18] (1) and [(Me)(4)N](13)[Cu5In30S54] (2) have been hydrothermally synthesized. Compound 1 is a 3D open framework built from T3 clusters, which has large porosity. Compound 2 has a double-layered structure constructed by T5 clusters. Our results indicate that tetramethylammonium ion is an efficient structure-directing agent for both ternary and quaternary indium sulfides. The optical and thermal properties have also been investigated. (C) 2014 Elsevier B.V. All rights reserved.