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One-Nanometer-Precision Control of Al2O3 Nanoshells through a Solution-Based Synthesis Route

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Indexed by:期刊论文

Date of Publication:2014-11-17

Journal:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals:SCIE、EI、Scopus

Volume:53

Issue:47

Page Number:12776-12780

ISSN No.:1433-7851

Key Words:Al2O3 coating; core-shell structure; layer thickness; lithium-ion batteries

Abstract:Forming uniform metal oxide nanocoatings is a well-known challenge in the construction of core-shell type nano-materials. Herein, by using buffer solution as a specific reaction medium, we demonstrate the possibility to grow thin nano-shells of metal oxides, typically Al2O3, on different kinds of core materials, forming a uniform surface-coating layer with thicknesses achieving one nanometer precision. The application of this methodology for the surface modification of LiCoO2 shows that a thin nanoshell of Al2O3 can be readily tuned on the surface for an optimized battery performance.

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