吕荣文
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教授
博士生导师
硕士生导师
性别:女
毕业院校:大连理工大学
学位:博士
所在单位:化工学院
办公地点:西部校区E420
联系方式:Email
电子邮箱:lurw@dlut.edu.cn
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铼联吡啶系列光敏染料的合成
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论文类型:期刊论文
发表时间:2004-05-15
发表刊物:高等学校化学学报
收录刊物:SCIE、PKU、ISTIC、CSCD
卷号:25
期号:05
页面范围:820-822
ISSN号:0251-0790
关键字:铼联吡啶络合物;光敏染料;纳米晶体光电池
摘要:In order to study the effects of the substituted groups on the properties of the complexes, a series of rhenium(Ⅰ) 2,2′-bipyridyl complexes [fac-(4,4′-di-COOEt-bpy)Re(CO) 3(X—pyridine)PF 6], where bpy is 2,2′-bipyridine and X is 4-methyl, 3-hydroxy, 4-hydroxy, 4-amino, or H, were synthesized with a yield more than 90%, and characterized by 1H NMR, 13C NMR, 2D-NMR( 1H- 1H COSY, HMBC, HSQC), ESI-MS and HRMS. The δ H values on the X—pyridine ring were shifted to up-field in 1H NMR and