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论文类型：期刊论文

发表时间：2015-12-01

发表刊物：CATALYSIS TODAY

收录刊物：SCIE、EI、CPCI-S、Scopus

卷号：258

页面范围：616-626

ISSN号：0920-5861

关键字：Platinum; Silver; Formaldehyde; Benzene; Nanoscale HZSM-5

摘要：A catalytic process including formaldehyde oxidation and benzene "storage-oxidation" cycling for simultaneously removal of formaldehyde and benzene is proposed, by using HZSM-5 supported PtAg bimetallic catalysts. HZSM-5 with different crystal size supported PtAg bimetallic catalysts were synthesized with the investigation focusing on HCHO oxidation at room temperature, benzene storage capacity at room temperature, and benzene catalytic oxidation at elevated temperature. Crystal size of HZSM-5 zeolite not only influences the dispersion of active metals of PtAg, and therefore influence their catalytic properties for formaldehyde and benzene oxidation, but also has great effects on benzene storage capacity and the thermal stability of the stored benzene, which is directly related to the release of benzene at elevated temperature. The ratio of Pt/Ag has an opposite effect on benzene storage capacity and formaldehyde and benzene oxidation properties. Considering these factors, PtAg (Pt/Ag = 1/1) supported on nanoscale HZSM-5 catalysts were found to be suitable for the proposed cycling process, good carbon balances being obtained for each cycle without the production of secondary pollutants. (C) 2015 Elsevier B.V. All rights reserved.