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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 精细化工国家重点实验室，副主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼F-212A
联系方式：0411-84986249
电子邮箱：dr.gaoyan@dlut.edu.cn
扫描关注
Nucleophilic Attack of Hydroxide on a Mn-V Oxo Complex: A Model of the O-O Bond Formation in the Oxygen Evolving Complex of Photosystem II
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论文类型：期刊论文
发表时间：2009-07-01
发表刊物：JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
收录刊物：EI、SCIE
卷号：131
期号：25
页面范围：8726-+
ISSN号：0002-7863
摘要：A manganese(III) corrole complex, 1, has been synthesized and used to study a potential mechanism for oxidation of water to molecular oxygen. Oxidation by t-BuOOH gave the Mn-V=O complex 2. Addition of hydroxide Led to release of oxygen via the Mn-IV complex 4 and regeneration of complex 1. It could be shown that the oxygen from O-18-labeted water was incorporated in both the formed molecular oxygen and the peroxy intermediate 4.