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论文类型：会议论文

发表时间：2017-05-08

发表刊物：75th Annual Technical Conference and Exhibition of the Society of Plastics Engineers, SPE ANTEC Anaheim 2017

收录刊物：EI、Scopus

卷号：2017-May

页面范围：132-137

摘要：In order to improve the low porosity, poor thermal stability and insufficient electrolyte wettability of commercial polyolefin separator, the novel PPESK fibrous membrane separator has been fabricated via electrospinning for the use of lithium-ion batteries. By the use of high-speed collection drum, the tensile strength of the electrospinning oriented PPESK fiber membranes increase significantly and reaches 18.9 MPa. Hot oven testing shows that oriented PPESK fiber membranes are thermally size stable at a high temperature of 220  C. The oriented PPESK fiber membrane exhibits high level of porosity (83%) and excellent electrolyte uptake (720%). Moreover, the ionic conductivity increases to 1.85 mS cm-1 compared with the 0.41mS cm-1 of commercial Celgard 2400 separator. In addition, the lithium-ion battery assembled with electrospinning oriented PPESK fiber membrane shows high capacity retention, stable cycle performance and excellent rate capability. Therefore, the electrospinning oriented PPESK fiber membrane is likely to be a promising candidate of high-power lithium-ion battery owing to its comprehensive outstanding characteristics.