Indexed by:期刊论文
Date of Publication:2018-09-01
Journal:DYES AND PIGMENTS
Included Journals:SCIE、EI、CPCI-S
Volume:156
Page Number:326-331
ISSN No.:0143-7208
Key Words:Photochromic; Carbothioamide; Proton transfer; Electrospinning
Abstract:Three carbothioamide derivatives with reversible P-type photochromic properties in the solid state were synthesized in a one-step reaction. Based on the single crystal structures, the FT-IR spectra and theory calculations, the proposed photochromic mechanism was the intermolecular proton transfer between the thio-keto and thioenol tautomer. Nanofibrous membranes were prepared by electrospinning, which showed improved reversible photochromic properties in comparison of the compound itself. This work may open a new pathway for design and synthesis of the new solid-state photochromic materials with high-performance.
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Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates
Gender:Male
Alma Mater:Jilin University
Degree:Doctoral Degree
School/Department:School of Chemistry Engineering
Discipline:Organic Chemistry. Applied Chemistry. Physical Chemistry (including Chemical Physics)
Business Address:西部校区E座208房间
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