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个人信息Personal Information
副教授
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：力学与航空航天学院
学科：工程力学. 车辆工程. 生物与纳米力学. 应用与实验力学. 制造工艺力学. 航空航天力学与工程
联系方式：Email: hanxiao@dlut.edu.cn
电子邮箱：hanxiao@dlut.edu.cn
Characterisation on the hygrothermal degradation in the mechanical property of structural adhesive: A novel meso-scale approach
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论文类型：期刊论文
发表时间：2020-02-01
发表刊物：COMPOSITES PART B-ENGINEERING
收录刊物：EI、SCIE
卷号：182
ISSN号：1359-8368
关键字：Adhesive bonding; Environmental degradation; Nanoindentation; Hygrothermal ageing; Water diffusion
摘要：Structural adhesives are being increasingly used for bonding of dissimilar materials, however environmental degradation remains a significant challenge limiting the bonding reliability. A common form of degradation comes from water ingress, regarding which there is limited quantitative understanding of how water diffusion affects the adhesive local mechanical properties. This work proposes a meso-scale approach to characterise the influence of water diffusion on local mechanical properties of structural adhesives at elevated temperature, aiming to develop a model of degradation due to water exposure. Gravimetric study was conducted on adhesives immersed in deionised and 5 wt% NaCl water, to obtain water diffusion characteristics. The immersed specimens were periodically removed from the aqueous environment and precisely cut to expose the internal section. The samples were then indented using nanoindentation to extract the modulus and hardness distribution. SEM observation was conducted to analyse the microscopic morphology and ageing mechanism. Experimental results revealed that water diffusion caused significant local (meso-scale) degradation in adhesive mechanical properties. Increase in local moisture concentration led to greater degradation as moisture gradually diffused inward. Comparing to salt water immersion, the elastic modulus and hardness of adhesive saturated in deionised water decreased by further 5.9% and 11.9%, respectively. The developed degradation model coupled with insights from ageing mechanism provides a detailed understanding of degradation in adhesive property due to water diffusion. The proposed characterisation approach can be readily applied to other adhesives. Furthermore, this model allows for degradation of such adhesives to be reasonably predicted through FE modelling effort.