景旭，研究员，博士生导师。通过对配位组装的精准控制，建立金属-有机超分子光催化酶模拟体系构建的平台方法。率先构筑金属-有机限域空腔包合染料的模拟酶催化体系。以第一作者和通讯作者在 Angew. Chem. Int. Ed (7篇)；J. Am. Chem. Soc (3篇) 和Nat. Commun.等高水平期刊发表论文。金属-有机限域催化条件下光诱导电子转移和电荷分离的关联机制的系列成果应邀在以金属-有机限域空间内的电子转移发表综述文章进行述评（Acc. Chem. Res. 2019, 52, 100），光响应体系的精准合成与功能调控获得2020年度辽宁省自然科学一等奖。

主要研究方向：

1. 超分子配合物的组装与模拟酶研究

采用配位自组装方法，设计新型具有限域空腔的金属-有机配合物。通过主客体的包和构建超分子体系，模拟生物酶的催化过程，构建高效催化体系。

2. 超分子光催化新能源新材料研究

研究光合作用、生物固氮等生命过程的过程机理。构建人工的模拟体系，实现光催化条件下氢气制备、CO₂的固定与转化、氮气的催化转化等生命过程的人工合成，制备高效、绿色的新能源催化材料。

3. 金属-有机框架催化手性药物中间体制备研究

通过自发拆分的方式，将非手性的有机配体与金属制备手性的金属有机配合物。经过手性诱导实现手性结构的统一和定向传递，为具有多手性中心的药物中间体制备提供经济、高效的催化制备途径。

课题组招收无机化学学硕、化学工程专硕，欢迎考生报考。

     主要代表论文

28. Mengrui Zhang, Dan Zhang, Xu Jing*, Baijie Xu and Chunying Duan*.Engineering NH₂-Cu-NH₂ Triple-atom Sites in Defective MOFs for Selective Overall Photoreduction of CO₂ into CH₃COCH₃. Angew. Chem. Int. Ed. 2024, e202402755

27.Yang Yang, Hanning Li, Youpeng Shi, Yuchen Wu, Xu Jing,* and Chunying Duan*.Modifying the Oxidative Potentials of Imines in a DyeLoaded Capsule for Photocatalytic Cyclization with Hydrogen Evolution. Angew. Chem. Int. Ed. 2024, 63, e202319605

26.Yang Yang, Xu Jing,* Youpeng Shi, Yuchen Wu, Chunying Duan.* Modifying Enzymatic Substrate Binding within a Metal–Organic Capsule for Supramolecular Catalysis. J. Am. Chem. Soc. 2023, 145, 10136-10148.

25. Huilin Huang, Xu Jing*, Jiangtao Deng, Changgong Meng, Chunying Duan.* Enzyme-Inspired Coordination Polymers for Selective Oxidization of C(sp3)–H Bonds via Multiphoton Excitation. J. Am. Chem. Soc. 2023, 145, 2170-2182.

24.Yang Yang, Xu Jing,* Jing Zhang, Fengyu Yang, Chunying Duan.* Modifying electron injection kinetics for selective photoreduction of nitroarenes into cyclic and asymmetric azo compounds. Nature Communications. 2022, 13, 1940.

23. Meiling Xu, Xu Jing,* Bin Sun, Cheng He, Joost N. H. Reek,* Chunying Duan.* Urea- Functionalized Fe4L6 Cages for Supramolecular Gold Catalyst Encapsulation to Control Substrate Activation Modes. Angew. Chem. Int. Ed. 2023, e202310420.

22. Zhong Wei, Xu Jing, * Yang Yang, Jiayou Yuan, Mingxu Liu, Cheng He, Chunying Duan. * A Platinum(II)‐Based Molecular Cage with Aggregation‐Induced Emission for Enzymatic Photocyclization of Alkynylaniline. Angew. Chem. Int. Ed. 2023, 62, e202214577.

21. Fengyang Yu, Xu Jing,* Yao Wang, Mingyang Sun, Chunying Duan.* Hierarchically Porous Metal–Organic Framework/MoS₂ Interface for Selective Photocatalytic Conversion of CO₂ with H₂O into CH₃COOH. Angew. Chem. Int. Ed. 2021, 60, 24849-24853.

20. Qingbo Shen, Jiali Chen, Xu Jing,* Chunying Duan.* Polyoxometalate-Embedded Metal–Organic Framework as an Efficient Copper-Based Monooxygenase for C(sp3)–H Bond Oxidation via Multiphoton Excitation. ACS Catal. 2023, 13, 9969-9978.

19. Xu Jing, Cheng He, Liang Zhao, Chunying Duan. * Photochemical Properties of Host–Guest Supramolecular Systems with Structurally Confined Metal–Organic Capsules. Acc. Chem. Res. 2019, 52, 1, 100–109

18. Leixin Hou, Xu Jing,* Huilin Huang, Chunying Duan. Merging Charge Transfer into Metal–Organic Frameworks to Achieve High Reduction Potentials via Multiphoton Excitation. ACS Appl. Mater. Interfaces. 2022, 14, 15307-15316.

17. Bingwen Zhong, Huilin Huang, Xu Jing, * Chunying Duan. Binuclear copper iodine cluster-based coordination sheets as photocatalysts for decarboxylative cyanation. Chem Comm. 2022, 58, 3961-3964.

16. Leixin Hou, Xu Jing,* Huilin Huang, Chunying Duan.* Interpenetrating dye-functionalized indium–organic frameworks for photooxidative cyanation and oxidative cyclization. J. Mater. Chem. A 2022, 10, 24320-24330.

15. Hanning Li, Yang Yang, Xu Jing, * Cheng He, Chunying Duan.* Triarylamine-based porous coordination polymers performing both hydrogen atom transfer and photoredox catalysis for regioselective α-amino C(sp3)–H arylation. Chem. Sci.  2021, 12, 8512-8520.

14. Meiling Xu, Bin Sun, David Poole, Eduard Bobylev, Xu Jing, * Jinguo Wu, Cheng He, Chunying Duan, * Joost N. H. Reek. * Broadening the catalytic region from the cavity to windows by the M6L12 nanospheres in cyclizations. Chem. Sci. 2023,  DOI: 10.1039/d3sc02998k

13. Huilin Huang, Xu Jing,* Bingwen Zhong, Changgong Meng, Chunying Duan.* Cuprous Cluster-Based Coordination Sheets as Photocatalytic Regulators to Activate Oxygen, Benzoquinone, and Thianthrenium Salts. ACS Appl. Mater. Interfaces. 2021, 13, 58498-58507.

12. Xiao Xu, Zhentao Li, Huilin Huang, Xu Jing,* Chunying Duan. A novel copper metal–organic framework catalyst for the highly efficient conversion of CO₂ with propargylic amines. Inorg. Chem. Front. 2022, 9, 3839-3844.

11. Fengkun Bai, Hanning Li, Xu Jing, * Chunying Duan. Visible-light-driven organic oxidation over CdS-doped metal–organic frameworks. Dalton Trans. 2023, 52, 8857-8863.

10. Leixin Hou, Xu Jing,* Huilin Huang, Chunying Duan. Integrating a fluorinated photoactive chromophore into metal–organic frameworks for selective trifluoroethylation of styrenes. Chem Comm. 2023, 59, 3407-3410.

9. Hanning Li, Yang Yang, Xu Jing,* Cheng He, Chunying Duan.* Multi‐Component Metal‐Organic Frameworks Significantly Boost Visible‐Light‐Driven Hydrogen Production Coupled with Selective Organic Oxidation. Chemistry – An Asian Journal 2021, 16, 1237-1244.

8. Mingyang Sun, Fengyang Yu, Jinfeng Wang, Yao Wang, Xu Jing, * Chunying Duan. d-NH2-MIL-125 doped with Cu NPs for light-driven hydrogen evolution. Chem Comm.  2023, 59, 8456-8459.

7. Xin Wang, Zhiduo Chang, Xu Jing,* Cheng He, Chunying Duan. Double-Helical Ag–S Rod-Based Porous Coordination Polymers with Double Activation: σ-Active and π-Active Functions. ACS Omega. 2019, 4, 10828-10833.

6. Linlin Yang, Xu Jing, Bowen An, Cheng He, Yang Yang, Chunying Duan.* Binding of anions in triply interlocked coordination catenanes and dynamic allostery for dehalogenation reactions. Chem. Sci. 2018, 9, 1050-1057.

5. Yang Yang, Hanning Li, Xu Jing,* Yuchen Wu, Youpeng Shi, Chunying Duan.* Dye-loaded metal–organic helical capsules applied to the combination of photocatalytic H2S splitting and nitroaromatic hydrogenation. Chem Comm. 2022, 58, 807-810.

4. Jiayou Yuan, Zhong Wei, Kesheng Shen, Yang Yang, Mingxu Liu, Xu Jing,* Chunying Duan.* Encapsulating electron-deficient dyes into metal–organic capsules to achieve high reduction potentials. Dalton Trans. 2022, 51, 10860-10865.

3. Yiying Zheng, Qingbo Shen, Zhentao Li, Xu Jing,* Chunying Duan. Two Copper-Containing Polyoxometalate-Based Metal–Organic Complexes as Heterogeneous Catalysts for the C–H Bond Oxidation of Benzylic Compounds and Olefin Epoxidation. Inorg. Chem. 2022, 61, 11156-11164.

2. Xu Jing, Cheng He, Yang Yang, Chunying Duan. A Metal–Organic Tetrahedron as a Redox Vehicle to Encapsulate Organic Dyes for Photocatalytic Proton Reduction J. Am. Chem. Soc.2015, 137, 3967-3974.

1. Xu Jing, Yang Yang, Cheng He, Zhiduo Chang, Joost N. H. Reek, Chunying Duan. Control of Redox Events by Dye Encapsulation Applied to Light-Driven Splitting of Hydrogen Sulfide. Angew. Chem. Int. Ed.2017, 56, 11759-11763.