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论文类型：期刊论文

发表时间：2015-02-01

发表刊物：MATERIALS RESEARCH INNOVATIONS

收录刊物：SCIE、EI、Scopus

卷号：19

期号：2

页面范围：81-85

ISSN号：1432-8917

关键字：Metallurgical grade silicon; Boron redistribution; Alloy solidification refining; Si-Al alloy melt; Solar power

摘要：Redistribution of boron during the silicon solidification refining process using an Si-Al melt has been studied by electron probe microanalysis and inductively coupled plasma mass spectrometry. The results and the effects of alloy composition, cooling rate and heating method on boron removal indicate that silicon can be purified by the segregation of boron to the alpha-Al component of the eutectic phase after the alloy solidification. Furthermore, use of lower cooling rate and Si-Al alloy with low Si content shows enhanced boron redistribution. The lowest refining ratio (0.17) and the highest removal fraction of boron (74.3%) were achieved in 22.8 at-% Si-Al alloy at a cooling rate of 3 K min(-1). Induction heating was used to obtain agglomerated Si plates and also recycled similar to 73.9% (by area) of byproduct (i.e. Si-Al alloy) from 35.4 at-% Si-Al alloy.