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    谢晴

    • 高级工程师    
    • 主要任职:无
    • 性别:女
    • 毕业院校:大连理工大学
    • 学位:博士
    • 在职信息:在职
    • 所在单位:环境学院
    • 学科:环境工程
    • 办公地点:环境楼A315
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    Direct photolysis of MeO-PBDEs in water and methanol: Focusing on cyclization product MeO-PBDFs

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    论文类型:期刊论文

    第一作者:Xue, Weifeng

    通讯作者:Chen, JW (reprint author), Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn MOE, Dalian 116024, Peoples R China.

    合写作者:Chen, Jingwen,Xie, Qing,Zhao, Hongxia

    发表时间:2015-11-01

    发表刊物:CHEMOSPHERE

    收录刊物:PubMed、EI、SCIE

    卷号:139

    页面范围:518-524

    ISSN号:0045-6535

    关键字:Methoxylated polybrominated diphenyl ethers; Direct photolysis; Photocyclization; Methoxylated polybrominated dibenzofurans; Density functional theory

    摘要:Polybrominated diphenyl ethers (PBDEs) and hydroxylated PBDEs can transform into polybrominated dibenzofurans (PBDFs) via photocyclization. However, it is unclear whether methoxylated PBDEs (MeO-PBDE5) can photocyclize to form MeO-PBDFs. In this study, 5-MeO-BDE-47, 5'-MeO-BDE-99 and 6-MeO-BDE-85 were selected as models to investigate their direct photolysis, especially photocyclization in two solvent environments (water and methanol) using simulated photochemical experiments and density functional theory (DFT) calculations. The experimental results showed that MeO-PBDE5 had faster direct photolysis reactions and higher quantum yields in methanol, and MeO-PBDFs could only be formed in a methanol solution of 5-MeO-BDE-47. The DFr results indicated that the lowest excited triplet state MeO-PBDEs can form dibenzofurans via direct cyclization pathways. Intra-annular H-elimination was found to be the rate-determining step for most cyclization pathways with high reaction barriers ( >19.7 kcal/mol), while 5-MeO-BDE-47 was found to have a distinct pathway for which the rate-determining step is ring closure with a low barrier (13.8 kcal/mol) in a methanol environment. For this pathway, H-elimination assisted by Br cleaved from an ortho-C-Br bond was observed with a 2.0 kcal/mol barrier. Thus, the OFT results reasonably explained the experimental findings, and the photocyclization of MeO-PBDEs depended on the specific Br-substitution patterns and specific effects of the environmental media. (C) 2015 Elsevier Ltd. All rights reserved.