A comparative study of the catalytic oxidation of HCHO and CO over Mn0.75Co2.25O4 catalyst: The effect of moisture
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- 论文类型：期刊论文
- 发表时间：2014-11-01
- 发表刊物：APPLIED CATALYSIS B-ENVIRONMENTAL
- 收录刊物：SCIE、EI
- 卷号：160
- 期号：1
- 页面范围：542-551
- ISSN号：0926-3373
- 关键字：Mn0.75Co2.25O4 catalyst; HCHO oxidation; CO oxidation; Water influence;
Stability
- 摘要：The influence of moisture on the activity and stability of Mn0.75Co2.25O4 catalyst for HCHO and CO oxidation was compared and investigated. Totally opposite effects of relative humidity (RH) on the reactions were observed: with increase of RH (0-90%), the activity for HCHO oxidation was enhanced, whereas the activity for CO oxidation was greatly decreased. However, in both cases the catalyst lifetime was prolonged in the presence of moisture (RH = 50%). Such modifications were directly evidenced by correlating in-situ DRIFTS data, TPO results and MS-IRAS studies, which clarified the effects of water on the activity and stability of Mn0.75Co2.25O4 catalyst for HCHO and CO oxidation. (C) 2014 Elsevier B.V. All rights reserved.
- 发表时间：2014-11-01
