- A novel bio-based phthalonitrile resin derived from catechin: synthesis and comparison of curing behavior with petroleum-based counterpart
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- 论文类型： 期刊论文
- 发表时间： 2018-03-01
- 发表刊物： POLYMER INTERNATIONAL
- 收录刊物： SCIE、EI
- 卷号： 67
- 期号： 3
- 页面范围： 322-329
- ISSN号： 0959-8103
- 关键字： bio-based; phthalonitrile resin; self-curing; catechin; thermosetting
- 摘要： The development of bio-based thermosetting resins with good thermal stability can potentially afford sustainable polymers as replacements for petroleum-based polymers. We report a practical route to a novel catechin-based phthalonitrile resin precursor (CA-Ph), which contains free phenolic hydroxyl groups that result in self-curing' at elevated temperatures to afford a thermostable polymer. Comparison of the performance of this CA-Ph resin with that of a conventional petroleum-based bisphenol A phthalonitrile resin (BPA-Ph; containing 5wt% of the curing agent 4,4-diaminodiphenylsulfone) revealed that CA-Ph exhibits a lower melting point and curing temperature. Cured CA-Ph resin retains 95% of its weight at 520 degrees C under a nitrogen atmosphere, which compares favorably with results obtained for BPA-Ph resin that retains 95% of its weight at a lower temperature of 484 degrees C. Kinetic results indicated that the curing reactions of both CA-Ph and BPA-Ph systems follow an autocatalytic mechanism. These results suggest that catechin is a useful bio-based feedstock for the preparation of self-curing and thermally stable phthalonitrile resins for advanced technological applications. (c) 2017 Society of Chemical Industry
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