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Indexed by:期刊论文

Date of Publication:2011-09-01

Journal:ENERGY & FUELS

Included Journals:Scopus、SCIE、EI

Volume:25

Issue:9

Page Number:4036-4042

ISSN No.:0887-0624

Abstract:A novel method to increase the tar yield through an integrated process of coal pyrolysis with CO2 reforming of methane by dielectric barrier discharge plasma was put forward. The pyrolysis of Shenmu (SM) subbituminous coal was carried out under different atmospheres, including N-2, H-2, and different plasmas of H-2, CH4, CH4/H-2, CO2/H-2, and CH4/CO2/H-2 (1/1/2, MG) to check the effect of the integrated process on improving the tar yield. Two kinds of coal samples, SM and Huolinhe (HLH) lignite were used in the integrated process to investigate the effects of gas flow rate, pyrolysis time, H-2 composition in the mixed gas (CH4/CO2/H-2), and discharge power on product yields. The results showed that the effect of different atmospheres on increasing the tar yield generally has the following order, especially at the temperature range 400-500 degrees C: MG plasma > CH4, plasma approximate to CH4/H-2 plasma approximate to CO2/H-2 plasma > H-2 plasma > H-2 > N-2. The tar yield of SM coal pyrolysis under MG plasma at the discharge power of 40W for 7 min is about 2.0 and 1.8 times as that under N-2 and H-2 at 400 degrees C, respectively.