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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 现任大连理工大学化工学院教授、博士生导师。同时担任“膜科学与技术”期刊编委，膜学会理事（筹），膜工业协会工程与应用专业委员会及特种分离膜专业委员会委员、中国兵工学会活性炭测试分析与应用研究分会委员等。
性别：男
毕业院校：大连工学院
学位：硕士
所在单位：化工学院
学科：化学工艺. 膜科学与技术. 功能材料化学与化工
办公地点：化工综合楼A201
联系方式：微信/电话 13500711370
电子邮箱：wangth@dlut.edu.cn
Facile preparation of ODPA-ODA type polyetherimide-based carbon membranes by chemical crosslinking
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论文类型：期刊论文
发表时间：2017-06-15
发表刊物：JOURNAL OF APPLIED POLYMER SCIENCE
收录刊物：SCIE、EI、Scopus
卷号：134
期号：23
ISSN号：0021-8995
关键字：carbon membranes; crosslinking; gas permeation; pyrolysis
摘要：A chemical crosslinking protocol was developed to prepare carbon membranes from 3,3,4,4-oxydiphthalic dianhydride-4,4-oxydianiline (ODPA-ODA) type polyetherimide on the support of phenolic resin sheets. The effects of support pretreatment, membrane-coating methods and crosslinking protocols on the resultant carbon membranes were investigated. The microstructure, functional group evolution, thermal stability, mechanics, morphology, and gas separation performance of samples were characterized by XRD, FTIR, TGA, mechanical testing technique, and gas permeation technique, respectively. Results have shown that the chemical crosslinking is more beneficial than the popular thermal crosslinking protocol to fabricate supported carbon membranes for the advantage of simple preparation process. In addition, spin-coating is superior to drop-coating in terms of good membrane formation on the support. Under the preferred preparation conditions of crosslinker ethylene glycol usage at 10 wt % and spin-coating, supported carbon membranes can be obtained with good hydrogen separation performance. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44889.