点击次数：

论文类型：期刊论文

发表时间：2015-02-01

发表刊物：JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS

收录刊物：SCIE、EI、Scopus

卷号：77

页面范围：23-29

ISSN号：0022-3697

关键字：Microporous materials; Thin films; Crystal growth; Microstructure

摘要：In the present work, a new dipcoating-rubbing method (DCRM) was developed to seed the surface of a macroporous carbon tube with a mixture of graphite and ZIF-8 nanoparticles. A continuous and low-defect ZIF-8 membrane was well formed on the seeded carbon tube by solvothermal growth. The DCRM involved a two-step process including first dipcoating a thin layer of the composite of graphite and ZIF-8 nanoparticles on the carbon surface and then rubbing the layer to form a stable seed layer. The graphite in the composite acting as binding agent could have two functions: (1) anchoring the ZIF-8 seeds onto the carbon surface; (2) smoothing the coarse surface of the macroporous carbon tube, thus forming a high quality ZIF-8 membrane. The as-prepared membrane was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and single gas permeation and was proved to be continuous and low-defect. The ideal selectivity of H-2/CH4 is 7.9 with a H-2 permeance of 7.15 x 10(-8) mot pa(-1) s(-1) m(-2), which is higher than its corresponding Knudsen diffusion value. We could therefore expect the ZIF-8 membrane supported on macroporous tubular carbon to achieve a high selectivity of H-2 over CH4 through a molecular sieving effect. (C) 2014 Elsevier Ltd. All rights reserved.